Usually you would need to change air correctors when changing mains.
When tuning a Weber you need to remember you have three circuits to consider -
Idle
Progression
Main
Idle and progression are fed from the idle jets, main from the main/emulsion tube/air corrector combo.
In these carbs the air correctors govern when the mains start feeding fuel and influence the overall rich/lean mixture at continued wider throttle openings.
Smaller air corrector brings on the main circut earlier and richens the upper range, larger air correctors do the opposite.
If you have reduced the mains, then on a relational base you will need to reduce the air correctors.
Cheers
James