I'll have a go and suggest cam timing and/or static timing is advanced to far as this can cause heating up and As with a fresh motor being tight also gives the higher temp than normal. If your motor has higher compression. Like 10.2:1 or similar the timing should be closer to TDC ,tho a dyno will get that spot on.
Also was the block hot tanked to remove rust scale and corrosion. If not , some water galleries could be blocked stopping its cooling efficency.
Hope you get it sorted cause there ain't nothing worse than constant overheating and being stuck in rush hr traffic.