that sounds exactly what my fairlane was doing thought it was the head gasket on its way out or cracked alloy head ... car was fine driving.... and cap off didnt do anything abnormal but as soon as i turnned engine off within couple minutes it was pissing out of overflow
after little bit of searching and doubble checking was the radiator cap seal and wrong radiator cap
psi rating ... the pressure was pushing the spring up to easy and would piss out of the over flow.. went and got one of a spare radiator and never did it again
just check that the seal is good and fits in the mouth of radiator fully some sit flat and seal.. some i notice made in china crap dont sit flush and only a portion of the seal is sealing so wont take much pressure to spring it up or one side and then you get the overflow pissing out